Reversible chain transfer catalyzed polymerization (RTCP): A new class of living radical polymerization
نویسندگان
چکیده
منابع مشابه
Modeling of Reversible Chain Transfer Catalyzed Polymerization by Moment Equations Method
A moment equations method was performed to study the Reversible chain Transfer Catalyzed Polymerization (RTCP) of styrene in 80°C. To do this, a kinetic scheme containing conventional free radical polymerization reactions and equilibrium reactions of RTCP was assumed. After obtaining mass balance equations, three moment equations were defined for free and dormant radicals and dead chains. M...
متن کاملmodeling of reversible chain transfer catalyzed polymerization by moment equations method
a moment equations method was performed to study the reversible chain transfer catalyzed polymerization (rtcp) of styrene in 80°c. to do this, a kinetic scheme containing conventional free radical polymerization reactions and equilibrium reactions of rtcp was assumed. after obtaining mass balance equations, three moment equations were defined for free and dormant radicals and dead chains. monom...
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Free radical polymerization is one of the most widely employed polymerization techniques. This technique is applied to prepare latexes to be used in paints, high molecular weight poly (methyl methacrylate) for safety glass (Plexiglas), or foamed poly (styrene) to be applied in coffee cups. Some advantages of radical polymerizations, with respect to other techniques, are the relative insensitivi...
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This review presents a short overview of recent developments in metal-catalyzed living radical polymerization, mainly focusing on our recent research studies related to the subject. Metal-catalyzed living radical polymerization or atom transfer radical polymerization, which was originally developed via evolution of the metal-catalyzed Kharasch or atom transfer radical addition to chain-growth p...
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ژورنال
عنوان ژورنال: Polymer
سال: 2008
ISSN: 0032-3861
DOI: 10.1016/j.polymer.2008.08.044